National Defense Fire Retardant Textiles
Chen Xuwei, President of the Military and Textile Branch of the China Industrial Textiles Association
The procurement and production of military textiles have evolved significantly over the years. As times change and market demands grow, both suppliers and buyers are increasingly willing to communicate and collaborate, leading to improved cost-effectiveness for military textiles. In terms of flame-retardant products, chemical flame-retardant fibers such as aramid 1313, aramid 1414, heterocyclic aramid, arylsulfone, carbon fiber, and vinylon are commonly used. These fibers serve as key components in protective clothing, anti-inflation suits, and other specialized applications.
Anti-yellow and compensation clothing require lightweight, durable, and flame-resistant materials with good dyeing properties, water resistance, and breathability. Notably, the Shenzhou 7 space suit features breakthroughs in high-temperature and radiation resistance. The outer layers are designed to be tear-resistant, heat-resistant, and capable of withstanding micro-meteorites and chemical exposure.
Flame-retardant fibers are also widely used in parachutes, including parachute canopies, ropes, straps, and covers. Modern parachutes demand materials that are lightweight, strong, flame-resistant, and able to maintain stability under various conditions. They must also offer controlled extension and adaptability to different air permeability levels.
Beyond special clothing, these fibers are used in block nets, gun covers, aircraft blankets, tents, and camouflage materials. For example, the Chameleon camouflage material developed by the Second Artillery Armament Research Institute is primarily composed of flame-retardant composite fibers.
Textile Flame Retardant Finishing Technology and Product Development
Cai Sheng, Ph.D. Supervisor of the Textile Chemistry Engineering Department at Donghua University
Fabric combustion typically involves three stages: thermal decomposition, ignition, and sustained burning. Flame retardants work by targeting different aspects of this process. Common mechanisms include endothermic reactions, free radical suppression, melting, non-flammable gas generation, and condensed-phase flame retardation.
Inorganic flame retardants not only provide fire resistance but also act as fillers. Organic options fall into phosphorus-based and halogen-based categories. Halogen-based ones, like chlorine and bromine compounds, are more common. Flame-retardant fibers are produced through methods such as coating, blending, copolymerization, grafting, and sheath-core spinning.
With the growth of the automotive and high-speed rail industries, the demand for high-quality flame-retardant fabrics has increased. Each train requires about 1,000 meters of seat fabric, while a car needs around 20 meters of textiles. In 2007, high-end automotive interiors required flame resistance, moisture absorption, breathability, color fastness, UV resistance, and anti-static properties—standards higher than those for regular textiles.
China’s domestic development in this area was limited, with high-end products dominated by Japan and Europe. Challenges included excessive smoke, poor heat resistance, and toxic emissions. To address this, we developed P-T expansive flame retardants that are formaldehyde-free, halogen-free, and offer excellent thermal and hydrolytic stability. These have been certified by international standards and are now used in trains operated by Siemens and others.
Why Use Protective Clothing
GEOFF, Personal Protection Expert from a Leading European Fiber Company
Proper use of flame-retardant protective clothing can prevent severe burns and save lives. Compared to the high costs of burn treatment, the cost of protective gear is minimal and highly effective. Wearing inappropriate clothing can lead to more severe injuries, especially in exposed areas.
Many countries have implemented laws requiring workers in hazardous environments to wear personal protective equipment (PPE). Major corporations like Shell and Alcoa enforce strict PPE policies for on-site workers. In China, similar requirements are being adopted across many industries.
Calculations show that even a 1% skin burn can result in hospitalization for 1.5 days, with an average stay of 19 days and daily costs exceeding $18,000. Hospitalization expenses can range from $200,000 to $700,000, sometimes surpassing $1 million.
Flame-retardant fabrics self-extinguish after the flame source is removed. Some treated fabrics may lose effectiveness after washing, while inherently flame-retardant fabrics, like aramid or cellulose-based fibers, maintain their properties over time. Testing standards include vertical burning tests, 12-second flame exposure, and limited afterflame time.
Future industries likely to invest in protective clothing include power companies, natural gas firms, steel mills, and fire services. Wearing the right gear can significantly reduce injury risks in dangerous environments.
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